Determining the Molarity of a Solution

Chemistry                                                                                            GIA 8-1

Unit: Solutions and Solubility                                                              Reading: Chapter 16

Working Mode: Pairs. Solve the problems on a separate sheet of notebook paper.  Each student must submit their own work on their own sheet of paper.

Learning Objective: Determine molarity of a solution and components of a solution based on various pieces of information.

Problem 1:  You are working with an HCl acidic solution in which 23.4 g of gaseous HCl was dissolved to make a 500. mL solution.

            Step 1: Determine the moles of HCl used.

            Step 2: Determine the molarity of the solution.

Problem 2:You have made an aqueous solution of sodium phosphate (Na3PO4: MM = 163.9 g) using 3.27 g of solute and making an aqueous solution with a volume of 250. mL.  Determine the concentration of your solution according to the following steps.

            Step 1: Determine the moles of Na3PO4 used.

            Step 2: Determine the molarity of the solution.

Problem 3: Oxygen gas is slightly soluble in water.  At 20oC [O2] = 1.38 x 10-3 M.  How many grams of O2 are dissolved in the water of an 80.0 L fish tank?

Problem 4:   NaCl has a solubility of 35.7 g NaCl per 100.g of H2O at 0oC.  If the resulting solution has a density of 1.12 g/mL, what would be the concentration in molarity of a saturated NaCl solution?

            Step 1: Determine the total mass of the solution.

            Step 2: Determine the volume of the solution in liters.

            Step 3: Determine moles of solute present.

            Step 4: Determine [NaCl].

Problem 5: An aqueous solution of sodium phosphate (Na3PO4: MM = 163.9 g) has a density of 1.15 g/mL and contains 22.0% by mass (mass of solute/mass of solution) of sodium phosphate.  Determine the number of moles of sodium ions (Na+) in one liter of the solution.  Don’t forget each sodium phosphate formula unit contains three sodium ions.